## Abstract Review: 74 refs.
Impedance analysis of electronically conducting polymers
โ Scribed by P. Ferloni; M. Mastragostino; L. Meneghello
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 532 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0013-4686
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โฆ Synopsis
Abstnwt-We
discuss in detail the equivalent circuits used to model the impedance of electronically conducting polymer systems and the procedure for the impedance analysis of these systems to account for deviation from the ideal behaviour. Impedance spectra of pyrrole-based and thiophene-based polymers of different thickness and at different values of injected charge in cells with liquid electrolytes and solid polymer electrolytes are reported, and the electrochemical parameters are evaluated and discussed.
๐ SIMILAR VOLUMES
The electrochemically polymerized conductive polymers were evaluated by an ac impedance measurement for use in a Li/polymer battery. The validity and the limit of ac impedance analysis for this case are discussed.
Polypyrrole (PPy) films were studied by ac impedance spectroscopy both in a free-standing membrane and in a modified electrode arrangement. The experimental results were analyzed by comparison with previously derived kinetic models, allowing to obtain, through a non-linear least-squares fitting proc
Abratract-A new model is elaborated which can explain some anomalies of the impedance spectra of polymer films on electrodes. The model assumes two capacitances associated with the double layers at the substrate/film and at the film/solution interfaces, respectively. The latter capacitance is consid