## Abstract With increasing environmental awareness, evaluating the potential of biopolymers as a substitute for traditional materials has been of great interest. Crystallization kinetics provides fundamental knowledge required for evaluation, playing vital role in determining the final properties
Impact of the nature and shape of cellulosic nanoparticles on the isothermal crystallization kinetics of poly(ε-caprolactone)
✍ Scribed by Gilberto Siqueira; Carole Fraschini; Julien Bras; Alain Dufresne; Robert Prud’homme; Marie-Pierre Laborie
- Book ID
- 113608413
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 659 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0014-3057
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📜 SIMILAR VOLUMES
## Abstract Summary: Phase behavior and isothermal crystallization kinetics of poly(__ε__‐caprolactone) (PCL) blends with tetramethyl polycarbonate (TMPC) and poly(styrene‐__co__‐acrylonitrile) with 27.5 wt.‐% acrylonitrile content have been investigated using broadband dielectric spectroscopy and
## Abstract Star‐shaped PCL with one to five arms were synthesized by ROP. They have the same crystal structure as linear PCL, indicating that the central cores are located in amorphous regions. The influence of arm length and number on crystallization and melting behavior were studied by DSC, POM,