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Impact of the Computational Method on the Geometric and Electronic Properties of Oligo(phenylene vinylene) Radical Cations

✍ Scribed by Geskin, V. M.; Grozema, F. C.; Siebbeles, L. D. A.; Beljonne, D.; Brédas, J. L.; Cornil, J.


Book ID
120392098
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
390 KB
Volume
109
Category
Article
ISSN
0022-3654

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Poly(2,5-dimethoxy-1,4-phenylene vinylene) (PDMoPV) prepared via the chlorine precursor route (CPR) exhibits absorption at a shorter wavelength than that obtained by the Wessling method. The polymer fluoresces at a maximum of 505 nm as compared to 540 nm by Wessling method. Both the fabricated ITO-P