Impact of Surface Immobilization and Solution Ionic Strength on the Formal Potential of Immobilized Cytochrome c
✍ Scribed by Petrović, Jelena; Clark, Rose A.; Yue, Hongjun; Waldeck, David H.; Bowden, Edmond F.
- Book ID
- 120980170
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 302 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0743-7463
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## Abstract We report on the effects of self‐assembled monolayer (SAM) dilution and thickness on the electron transfer (ET) event for cytochrome c (CytC) electrostatically immobilized on carboxyl terminated groups. We observed biphasic kinetic behavior for a logarithmic dependence of the rate const
Modified electrodes were obtained by electrodeposition on Pt of polypyrrole (PP) from aqueous solutions. The electrode8 obtained in the absence of cytochrome c were tested by cyclic voltammetry in aqueous solutions containing different supporting electrolytes. The current corresponding to the oxidat