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Impact of O–Si–O bond angle fluctuations on the Si–O bond-breakage rate

✍ Scribed by Stanislav Tyaginov; Viktor Sverdlov; Ivan Starkov; Wolfgang Gös; Tibor Grasser


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
611 KB
Volume
49
Category
Article
ISSN
0026-2714

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29Si and17O NMR investigations on Si−O−T
✍ Dagobert Hoebbel; Thomas Reinert; Helmut Schmidt 📂 Article 📅 1996 🏛 Springer 🌐 English ⚖ 816 KB

The structural units in diphenylsilanediol/titanium-isopropoxide solutions with molar ratio Si:Ti between 1 :O. 1 and I:5 were examined by means of 29Si and "0 NMR. The main component in solutions with molar ratio Si/Ti = 1 :O. 1 is the chain-like octaphenyltetrasiloxanediol. With increasing Ti-iso