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Impact of molecule-based magnetic materials: A critical outlook

✍ Scribed by Eva Rentschler; Marco Affronte; Carlo Massobrio; Pierre Rabu; Jaume Veciana


Book ID
113913731
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
75 KB
Volume
11
Category
Article
ISSN
1293-2558

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A cyclic complex [Ni(12)(chp)(12)(O(2)CMe)(12)(thf)(6)(H(2)O)(6)] (1) has been synthesised and studied (chp=6-chloro-2-pyridonate). Complex 1 exhibits ferromagnetic exchange between the S=1 centres, giving an S=12 spin ground state. Detailed studies demonstrate that it is a single-molecule magnet wi