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Impact of Fluorination and Side-Chain Length on Poly(methylpropenoxyalkylsiloxane) and Poly(alkyl methacrylate) Solubility in Supercritical Carbon Dioxide

✍ Scribed by McHugh, Mark A.; Garach-Domech, Alberto; Park, Il-Hyun; Li, Dan; Barbu, Eugen; Graham, Paul; Tsibouklis, John

Book ID
126888336
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
61 KB
Volume
35
Category
Article
ISSN
0024-9297

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Structural Reasons for Restricted Backbo
Structural Reasons for Restricted Backbone Motion in Poly(n-alkyl methacrylates): Degree of Polymerization, Tacticity and Side-Chain Length
✍ Michael Wind; Robert Graf; Sabine Renker; Hans Wolfgang Spiess πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 480 KB

## Abstract **Summary:** The complex dynamics of poly(__n__‐alkyl methacrylates) is studied by advanced ^13^C NMR spectroscopy as well as mechanical and dielectric relaxation. Extended backbone conformations are identified as the molecular units involved in structural relaxation. From the variation