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Impact of Backbone Architecture on the Solubility of Fluorocopolymers in Supercritical CO 2 and Halogenated Supercritical Solvents: Comparison of Poly(vinylidene fluoride- co -22 mol hexafluoropropylene) and Poly(tetrafluoroethylene- co -19 mol hexafluoropropylene)

โœ Scribed by Mertdogan, Cynthia A.; DiNoia, Todd P.; McHugh, Mark A.


Book ID
126297691
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
132 KB
Volume
30
Category
Article
ISSN
0024-9297

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Cloud-point data to 280ยฐC and 2800 bar are reported for a binary mixture of poly(tetrafluoroethylene-co-19.3 mol % hexafluoropropylene) (FEP 19 ) in fluoroform (CHF 3 ) and for ternary mixtures of FEP 19 -CHF 3 -sulfur hexafluoride (SF 6 ) and FEP 19 -CO 2 -SF 6 . FEP 19 does not dissolve in CHF 3 a