Impact fracture behavior of nylon-6/ABS blends

✍ Scribed by A. Mamat; T. Vu-Khanh; P. Cigana; B. D. Favis

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 299 KB
• Volume: 35
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19971130)35:16<2583::aid-polb2>3.0.co;2-r

✦ Synopsis

Tensile and impact properties of uncompatibilized nylon-6/ABS blends have been studied over the entire range of compositions. The blends were prepared by extrusion and, subsequently, injection molded into tensile specimens and rectangular plaques. The impact fracture performance was characterized using recently proposed models based on fracture mechanics, for various fracture behaviors. The results showed that nylon-6 breaks in a brittle manner. With the addition of ABS, the blend exhibits the same behavior with a slightly lower impact resistance up to about 60 wt %. A sudden jump in the value of impact fracture energy is observed around 70 wt % ABS with a brittle-ductile transition in the mechanism of fracture. The transition in fracture mechanisms is confirmed through observation of the fracture surfaces by scanning electron microscopy (SEM). Tensile tests showed that the elongation at break increases only slightly between 0 and 50% ABS content, but a significant jump occurs around 70% ABS, reaching a 6-fold increase in comparison to that of the pure components. SEM observation of etched samples shows that a cocontinuous morphology occurs around 70 wt % ABS. The peak observed for the elongation at break and the jump in impact performance, as well as the onset of brittleductile transition, are attributed to this morphological effect.