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Immobilization and chiral recognition of 3,5-dimethylphenylcarbamates of cellulose and amylose bearing 4-(trimethoxysilyl)phenylcarbamate groups

✍ Scribed by Shouwan Tang; Tomoyuki Ikai; Masashi Tsuji; Yoshio Okamoto


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
199 KB
Volume
22
Category
Article
ISSN
0899-0042

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Immobilization of 3,5-dimethylphenylcarb
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## Abstract The 3,5‐dimethylphenylcarbamates of cellulose and amylose were effectively immobilized onto plain silica gels as chiral packing materials (CPMs) for HPLC by means of intermolecular polycondensation of triethoxysilyl groups introduced with (3‐glycidoxypropyl)triethoxysilane. The immobili

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## Abstract The 3,5‐dichlorophenylcarbamates (**2**) of cellulose bearing a small amount of 3‐(triethoxysilyl)propyl residues were synthesized by a one‐pot process and immobilized onto a silica gel through intermolecular polycondensation of the triethoxysilyl groups. The obtained cellulose derivati