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Iminium ion cyclizations. Highly stereoselective synthesis of substituted tetrahydroisoquinoline derivatives

✍ Scribed by Bruce E. Maryanoff; David F. McComsey

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 235 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95527-3

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✦ Synopsis

Cationic cyclizations of acyliminium ions 5 (Rl = phenyl) occur with high stereoselectivity, which is suggested to originate in the intermediate arenium ions.

Stereoselective

syntheses of substituted alkaloid ring systems are important to synthetic

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