Imination of N-methylazinium salts by liquid ammonia/potassium permanganate
✍ Scribed by M. Woźniak; D. J. Buurman; H. C. Van Der Plas
- Book ID
- 112127876
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1985
- Tongue
- English
- Weight
- 371 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-152X
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## Abstract 5‐ and 8‐Nitroisoquinoline and some of their derivatives are aminated in a liquid ammonia solution of potassium permanganate to yield the corresponding 6‐ and 7‐amino compounds. From 5,7‐dinitroisoquinoline the 6,8‐diamino derivative is obtained; 1‐nitroisoquinoline has been found to be
## Abstract 5‐ and 6‐Nitroquinoxalines and some of their derivatives are aminated in a liquid ammonia solution of potassium permanganate to yield the corresponding 2‐ and/or 3‐ and/or 5‐amino compounds. Quantum‐chemical calculations are made to explain the regioselectivity of the amination reaction