Imidotitanium Complexes with Heteroallyl
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Editha MΓΌller; JΓΌrgen MΓΌller; Falk Olbrich; Wolfgang BrΓΌser; Wolfram Knapp; Dirk
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Article
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1998
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John Wiley and Sons
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English
β 386 KB
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Treatment of Ti(NtBu)Cl 2 (py) 2 (1, py = pyridine) with bulky stitution products [PhC(NiPr) 2 ] 2 Ti(NtBu)(py) (6) and [Ph 2 P(NSiMe 3 ) 2 ] 2 Ti(NtBu) (7). The bis(pyridine) adduct heteroallylic ligands in a 1:1 molar ratio affords the monosubstituted derivatives [PhC(NSiMe 3 ) 2 ]Ti(NtBu)Cl(py) 2