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Imaging and probing catalytic surface reactions on the nanoscale: Field Ion Microscopy and atom-probe studies of O2–H2/Rh and NO–H2/Pt

✍ Scribed by Thierry Visart de Bocarmé; Thoi-Dai Chau; Norbert Kruse


Publisher
Springer
Year
2006
Tongue
English
Weight
731 KB
Volume
39
Category
Article
ISSN
1022-5528

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✍ D. Lackey; J. Schott; J.K. Sass; S.I. Woo; F.T. Wagner 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 413 KB

By coadsorbing hydrogen and water on Pt( 111) and Cu( I lo), and isotopically substituting (H),.,by (D)ad, we have unambiguously identified the occurrence of the electrochemical reaction (H)ad+ (H\*O),,~(H,O+),+e,,,, in UHV. On Pt( I I1 ), a substantial fraction of the hydrogen is oxidized to (H,O+)