III. Novitates sinenses et japonicae.

Applications Synthétiques de la Cyclisat

Applications Synthétiques de la Cyclisation d′Alcools Tertiaires γ-Éthyléniques en α-Bromotétrahydrofurannes sous l'action du N-Bromosuccinimide. III. Synthèse du Triméthyl-2,6,10-hydroxy-10-dodécatriène-2,6,11-al (trans/trans et trans/cis), Hydroxy-Aldéhyde apparenté aux Sinensals

✍ Edouard Demole; Paul Enggist 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 German ⚖ 284 KB

## Abstract The reaction of 1‐formyl‐ethylidene‐triphenylphosphorane with __trans__‐ and __cis__‐4,8‐dimethyl‐8‐hydroxy‐deca‐4,9‐dienal (**7**) obtained from (±)‐nerolidol through a novel bromination/oxidation/debromination sequence, afforded 2,6,10‐trimethyl‐10‐hydroxy‐dodeca‐2,6‐11‐trienal **6**