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Identification of the EPR-Active Iron-Nitrosyl Complexes in Mammalian Ferritins

✍ Scribed by Lee, Minghe; Arosio, Paolo; Cozzi, Anna; Chasteen, N. Dennis

Book ID
126332255
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
1001 KB
Volume
33
Category
Article
ISSN
0006-2960

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✍ Lijuan Li; John R. Morton; Keith F. Preston 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 541 KB

## Abstract The oxidation of Fe(NO)~2~(CO)~2~ by tetracyanoethylene (TCNE), by the nitrosonium ion (NO^+^), or by electrolysis in polar solvents was studied by EPR spectroscopy. A number of long‐lived (τ~1/2~ of the order of hours) free radicals were detected in the early stages of reaction, all ha