## Abstract The catalytic mechanism of molybdenum containing CO dehydrogenase has been studied using hybrid DFT methods with quite large chemical models. The recent highβresolution Xβray structure, showing the surprising presence of copper linked to molybdenum, was used as a starting point. A pathw
Identification of the CO oxidation site of CO dehydrogenase by EPR and ENDOR studies of the cyanide-inhibited state.
β Scribed by Mark E. Anderson; Victoria J. DeRose; Brian M. Hoffman; Paul A. Lindahl
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 89 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The crystal structure of cobalt-substituted azurin from Pseudomonas aeruginosa has been determined to final crystallographic R value of 0.175 at 1.9 Γ resolution. There are four molecules in the asymmetric unit in the structure, and these four molecules are packed as a dimer of dimers. The dimer pac
We have characterized the adsorption of Co(II) on the (0001) and (11 02) surfaces of β£-Al 2 O 3 single crystals under ambient conditions using polarization-dependent grazing-incidence X-ray absorption fine structure spectroscopy, in combination with bond valence modeling. Co(II) ions were found to b