Identification of Putative Peroxide Intermediates of Peroxidases by Electronic Structure and Spectra Calculations
โ Scribed by Harris, Danni L.; Loew, Gilda H.
- Book ID
- 125935539
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 213 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Computational studies exploring the extent to which differences in proximal axial ligands modulate structure, spectra, and function of peroxidases have been performed. To this end, three heme models of compound I were characterized differing only in the axial ligand. The axial ligands considered wer
Electronic absorption and resonance Raman spectra of various peroxidases and selected site-directed mutants are reported. These results and the X-ray crystal structure data are critically analyzed and underline the differences that exist between the crystal and solution states. The effect of the vin