Identification of nitrogen functional groups in Athabasca bitumen
β Scribed by Speros E. Moschopedis; Randall W. Hawkins; James G. Speight
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 483 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0016-2361
No coin nor oath required. For personal study only.
β¦ Synopsis
Reactions of resins, asphaltenes and model nitrogen compounds with acetic anhydride and with trifluoroacetic anhydride yield compounds which provide indications that the predominant nitrogen functional groups in resins and asphaltenes (from Athabasca bitumen) exist as imino groups of the carbazole-type.
Evidence for this was obtained from infrared and F" nuclear magnetic resonance studies.
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The plasticizing effectiveness of hydrocarbons in Athabasca bitumen (i.e. the extent of reduction in viscosity of the bitumen caused by hydrocarbons) depends on the molecular structure of the hydrocarbon and the molecular interaction between hydrocarbon and bitumen. High molecular weight. branching,
Infrared and chemical studies of the resin fraction isolated from Athabasca bitumen indicate that oxygen in these fractions exists predominantly as ester functions. Evidence for this was obtained from hydrolysis, acetylation and methylation reactions.
## Abstract Experimental data for the diffusivity of carbon dioxide, methane, ethane and nitrogen in Athabasca bitumen are presented in the range 25β90Β°C at 4 and 8 MPa. The diffusivity of these gases has been determined as a function of gas concentration in bitumen using a nonβintrusive experimΜen