The new oxoisoaporphines 7H-dibenzo[de,h]quinolin-7-one, 5-methoxy-7H-dibenzo[de,h]quinolin-7-one, 5methoxy-6-hydroxy-7H-dibenzo[de,h]quinolin-7-one, 5hydroxy-7H-dibenzo[de,h]quinolin-7-one and 5-methoxy-6H-dibenzo[de,h]quinolin-6-one were prepared either by oxidation of their 2,3-dihydro derivative
Identification of modified natural porphyrin isomers: 1H and 13C NMR assignments by NOESY and reverse heteronuclear shift correlation
✍ Scribed by Arnaud Bondon; Marie Autret; Gérard Simonneaux
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 410 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The efficiency of two‐dimensional homonuclear ^1^H^1^H NOE spectroscopy in characterizing and fully assigning the ^1^H NMR spectra of several isomers of meso‐ or ring‐substituted deuteroporphyrins is demonstrated. The carbon resonances of the skeleton and the substituents were fully assigned using two‐dimensional reverse heteronuclear shift correlation spectroscopy.
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