Identification of 3-deoxy-manno-2-octulosonic acid, 3-deoxy-5-O-methyl-manno-2-octulosonic acid and 3-deoxy-lyxo-2-heptulosaric acid in the cell wall (theca) of the green alga Tetraselmis striata Butcher (Prasinophyceae)
✍ Scribed by Burkhard BECKER; Karl HÅRD; Michael MELKONIAN; Johannis P. KAMERLING; Johannes F. G. VLIEGENTHART
- Book ID
- 115126321
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 580 KB
- Volume
- 182
- Category
- Article
- ISSN
- 1432-1327
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The reaction of the peracetate methyl esters of N-acetylneuraminic acid (Neu5Ac), 3-deoxyq~glycero-D-galacto-2-nonulosonic acid (Kdn), and 3-deoxy-D-manno-2-octulosonic acid (Kdo) with trimethylsilyl trifluoromethanesulfonate (CF3SO3SiMe 3) has been reinvestigated. We have found that the choice of s
The identification of the peracetylated methyl glycosides of 3-deoxy-o-
The favoured conformations of a series of C-glycosyl derivatives of 4,5:7,8-di-O-isopropylidene-3deoxy-D-munno-2-octulosonic acid (Kdo) esters were analyzed by n.m.r. spectroscopy and in one instance by X-ray crystallography. The Kdo derivatives were found to adopt a skew-boat conformation (& + OS,)