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Identification and Synthesis of Elymniafuran, a New Monoterpene from the Butterfly Elymnias thryallis

✍ Scribed by Schulz, Stefan ;Steffensky, Mirjam ;Roisin, Yves


Book ID
102905101
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
576 KB
Volume
1996
Category
Article
ISSN
0947-3440

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✦ Synopsis


Abstract

The main constituent of the scent gland secretion of the tropical butterfly Elymnias thryallis (Lepidoptera: Satyridae) could be identified as (S)‐2‐methyl‐1‐(4‐methyl‐2‐furyl)‐3‐buten‐2‐ol (elymniafuran, 3). It is accompanied by small amounts of (E)‐ and (Z)‐4‐methyl‐(2‐methyl‐1,3‐butadienyl)‐furan (4) as well as the spiro acetal 3,9‐dimethyl‐1,6‐dioxaspiro[4.5]dec‐3‐ene (10). The structural assignment of these new natural products as well as the synthesis and enantiomeric separation by chiral gas chromatography are described.


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