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Identification and Kinetic Study of the Peroxymalonyl Radical in the Aerobic Oxidation of Malonic Acid by Cerium(IV)

✍ Scribed by Neumann, B.; Mueller, S. C.; Hauser, M. J. B.; Steinbock, O.; Simoyi, R. H.; Dalal, N. S.


Book ID
125960138
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
288 KB
Volume
117
Category
Article
ISSN
0002-7863

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Kinetic Study of the Oxidation of Dimeth
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The kinetics of the oxidation of dimethylsulfoxide by Cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is dis- ## Kinetische Untersuchung der Oxidation von Dim