The contact angle, θ , of a small bubble on a flat solid substrate was measured as a function of bubble radius, R. The observed deviation of the contact angle from 90 • can be accounted for in terms of a negative line tension, τ . The measured values of |τ |/γ f , where γ f is the film tension, rang
I. Transition regions, line tensions and contact angles in soap films
✍ Scribed by J.A. De Feijter; A. Vrij
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 778 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-0728
No coin nor oath required. For personal study only.
✦ Synopsis
An analysis is given of the thickness profile of a circular soap film and its Plateau border. It shows that in principle the thickness as a function of the radial distance, h(r), for a single film, can provide details of the interaction free energy AF(h) over a large range of h. The transition region between film and Plateau border where h(r) rapidly changes from microscopic to macroscopic values contains most information. With a simple model of AF(h), the profile and extension of the transition region is calculated for some "first black" soap films.
It is shown that to complete the macroscopic description of a liquid sheet, a line tension must be introduced. A theoretical expression for this line tension is given and its physical meaning is discussed. Some values are calculated using the same AF(h) as before.
📜 SIMILAR VOLUMES
the intrinsic contact angle u i that a liquid drop makes with An approximate theory for calculating the line tension in a an ideal solid surface (2, 8) solid-liquid-fluid system is presented and demonstrated for a solid-liquid-vapor system. The line tension is shown to depend on the contact angle. C