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I. Mechanism of Solvolysis of Triphenylmethyl Chloride in Hydroxylic Solvents 1—3

✍ Scribed by Swain, C. Gardner; MacLachlan, Alexander

Book ID
126191846
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
977 KB
Volume
82
Category
Article
ISSN
0002-7863

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Solvolysis–decomposition of N-1-adamanty
Solvolysis–decomposition of N-1-adamantyl-N-p-tolylcarbamoyl chloride in hydroxylic solvents
✍ Dennis N. Kevill; Veena Upadhyay 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 77 KB

In hydroxylic solvents, N-1-adamantyl-N-p-tolylcarbamoyl chloride undergoes a facile rate-determing ionization with very little assistance from nucleophilic solvation (very low sensitivity to changes in solvent nucleophilicity). In the relatively nucleophilic aqueous ethanol or aqueous acetone, the