✦ LIBER ✦
I. Acetolysis studies of di-, tetra- and hexamethylated cyclopentyl tosylates
✍ Scribed by A.Paul Krapcho; David E. Horn
- Book ID
- 104211889
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 258 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Brown and Chloupek (1) have reported that the introduction of a-methyl groups in s series of 1-chloro-1-methylcyclopentsnes csuses an increase in the ethsnolysis rate (e.g., l-chloro-1,2,2,5,%pentsmethylcyclopentsne reacts 82 times faster than 1-chloro-1-methylcyclopentsne). The increased solvolysia rstes of the a-methyl substituted compounds in these tertiary systems have been rationalized in terms of increased ground state steric strain.