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Hysteresis Effects for Sorption in Glassy Polymers

โœ Scribed by Vrentas, J. S.; Vrentas, C. M.


Book ID
125943047
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
160 KB
Volume
29
Category
Article
ISSN
0024-9297

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Sorption in glassy polymers
โœ Vrentas, J. S.; Vrentas, C. M. ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 987 KB
Integral sorption in glassy polymers
โœ J.S. Vrentas; C.M. Vrentas ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 803 KB

A new theory is developed for integral sorption and desorption processes in glassy polymers. The theory can describe both case II diffusion and the classical case of Fickian diffusion. Predictions of the theory are compared with general experimental observations.

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โœ J. S. Vrentas; C. M. Vrentas ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 160 KB ๐Ÿ‘ 1 views

Anomalous sorption curves have often been observed for differential sorption experiments in glassy polymers. A model is proposed to describe this non-Fickian behavior. This model is based on the presence of interfacial resistance caused by slow rate processes at the phase boundary. Predictions of th