Hypervalent iodine(III) oxidation catalyzed by quaternary ammonium salt in micellar systems

✍ Scribed by Hirofumi Tohma; Shinobu Takizawa; Hiroaki Watanabe; Yasuyuki Kita

• Book ID: 104259379
• Publisher: Elsevier Science
• Year: 1998
• Tongue: French
• Weight: 227 KB
• Volume: 39
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(98)00828-4

✦ Synopsis

Catalytic activation of iodosobenzene (Phi=O) by cetyltrimethylammonium bromide (CTAB) allows sulfide oxidation reaction to occur in high yields under mild conditions in a variety of solvents. This PhI=O activation may be due to the formation of micellar or reversed micellar systems.