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Hypersensitive Mechanistic Probe Studies of Cytochrome P450-Catalyzed Hydroxylation Reactions. Implications for the Cationic Pathway

✍ Scribed by Toy, Patrick H.; Newcomb, Martin; Hollenberg, Paul F.


Book ID
126322751
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
199 KB
Volume
120
Category
Article
ISSN
0002-7863

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit