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Hyperpolarization properties of pyridinium and quinolinium salts determined by hyper-Rayleigh scattering

✍ Scribed by Eve Chauchard; Catherine Combellas; Eric Hendrickx; Grégoire Mathey; Charles Suba; André Persoons; André Thiebault


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
566 KB
Volume
238
Category
Article
ISSN
0009-2614

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✦ Synopsis


The quadratic hyperpolarizabilities of a series of pyridinium and quinolinium salts are measured by hyper-Rayleigh scattering in solution. These salts present high hyperpolarizabilities combined with good transparencies in the visible region of the spectrum. The higher efficiency of the teraryl over the biaryl for the conjugation path between the donor and the acceptor groups is clearly evidenced.