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Hyperfine structure constants of (d+s)3 states in La I and the Zr II and Hf II isoelectronic sequences

✍ Scribed by Donald R. Beck

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 169 KB
Volume: 65
Category: Article
ISSN: 0020-7608
DOI: 10.1002/(sici)1097-461x(1997)65:5<555::aid-qua20>3.0.co;2-0

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✦ Synopsis

Accurate results for hyperfine structure HFS constants of d q s states often require the inclusion of both correlation and relativistic effects. Without these, Dirac᎐Fock HFS constants may have the wrong sign, the energies of uppermost d n levels may be wrong by over 1 eV. Here, we demonstrate that these problems persist well into an isoelectronic sequence, and identify the principle configurations needed to achieve accurate results.

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