By introducing the IR-UV pump-probe technique to detect molecular quantum beats, this phenomenon is utilized as a Doppler-free time domain spectroscopy for the electronic ground state. The technique is demonstrated with Stark quantum beats of vibrationally excited So levels to determine the electric
Hyperfine quantum beat spectroscopy of a polyatomic molecule in a weak magnetic field with polarized light
✍ Scribed by J. Mühlbach; M. Dubs; H. Bitto; J.Robert Huber
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 397 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Resolved Zeemnn splirtings in molecular quantum beats arc used for the lirst time to ass@ hypertine components of n rriplet sublevel of a polyatomic molecule. I'rom linear Zeeman splittings and level anti-crossing, Land6 factors and spinorbit coupling clemcnts arc determined for propynal. Specitic Zeeman components are identified by changing the laser polarizalion.
📜 SIMILAR VOLUMES
The feasibility of determining nuclear quadrupole hyperfine splittings in the ground electronic state of a polyatomic molecule using a double resonance quantum beat method has been demonstrated. Pyrimidine molecules were coherently excited into single rotational states of the So 201 ( 13a ~) vibrati