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Hyperfine evidence of strong double exchange in multimetallic {[Fe4S4]-Fe} active center of Escherichia coli sulfite reductase

✍ Scribed by M. I. Belinsky


Book ID
106232739
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
165 KB
Volume
1
Category
Article
ISSN
1432-1327

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Induced paramagnetism and hyperfine inte
✍ Moisey I. Belinsky πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 639 KB

The spin-coupling model of the {[Fe4S4]-siroheme} center of the active site of sulfite reductase is developed. The tetmmer-siroheme coupling 2JthS j -s h results in the induced paramagnetism of individual ions of the Fe/S tetramer which = ~ \_\_ 33/j .j. provides non-zero effective hyperfine consta