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Hyperfine constants for the ethyl radical in the gas phase

✍ Scribed by Paul W. Percival; Jean-Claude Brodovitch; Siu-Keung Leung; Dake Yu; Robert F. Kiefl; David M. Garner; Donald J. Arseneau; Donald G. Fleming; Alicia Gonzalez; James R. Kempton; Masayoshi Senba; Krishnan Venkateswaran; Stephen F.J. Cox


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
403 KB
Volume
163
Category
Article
ISSN
0009-2614

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The kinetics of the reactions CsH,+OH( t M) +products ( + M ) ( I ) were studied at room temperature by pulse radiolysis of C2H6/H20/SFb mixtures. The ethyl radical decay was followed by monitoring the UV absorption signals at 205 nm. The experimentally determined value of k, is (7.1 f 1.0) x lOto M