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Hyperfeinstruktur in den ESR-spektren von thermisch behandeltem polyphenylacetylen

✍ Scribed by Bartl, Anton ;Freudenberg, Getraud ;Fröhner, Jürgen ;Pietraß, Bernhard ;Wuckel, Lothar


Publisher
Wiley (John Wiley & Sons)
Year
1983
Weight
227 KB
Volume
184
Category
Article
ISSN
0025-116X

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✦ Synopsis


Abstract

A highly resolved ESR spectrum of dissolved polyphenylacetylene has been measured at 120°C. It was found by simulation that the protons of three phenyl groups and two protons of the carbon chain contribute to the spectrum. The structure of the corresponding paramagnetic centre is given.


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Tabelle 1 Einige Eigenschaften 025°C ausgewiihlter Glaser in Q-l cm-1 Nr . Zusammenset zung Ti 7 a 25-200°C Dichte in Mol-26 in "C in grd-l in g . ~m -~ GeSe, GeSe PbSe 1 30 55 15 246 14,28. lo-' 5,161 f 0,001 2,O. 10-l' 2 30 47 23 239 15,03 \* 1 0 P 5,456 f 0,003 3,2 . lo-'' 3 30 40 30 239 15,94 \*