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Hypercoordinate Silicon Complexes of (O,N,N′ vs. O,N,O′) Schiff Base Type N-(2-Carbamidophenyl)imines: Examples of Exclusively O-Silylated Carbamides

✍ Scribed by Alexander Kämpfe; Edwin Kroke; Jörg Wagler

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
287 KB
Volume
2009
Category
Article
ISSN
1434-1948

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Single-Atom O-Bridged Urea in a Dinickel
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✍ Soumen Mukherjee; Thomas Weyhermüller; Eberhard Bothe; Karl Wieghardt; Phalguni 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 251 KB 👁 2 views

## Abstract A pentadentate phenol‐containing ligand (H~3~L) with N~2~O~3~ donor atoms yields Ni^II^~2~ (1), Ni^II^~4~ (2), Cu^II^~2~ (3) and Cu^II^~4~ (4) complexes, which have been structurally characterized by X‐ray diffraction. Complex 1 contains a single‐atom __O__‐bridged urea. The compounds w