๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Hyperbranched polymers: a promising new class of materials

โœ Scribed by Mitsutoshi Jikei; Masa-aki Kakimoto


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
784 KB
Volume
26
Category
Article
ISSN
0079-6700

No coin nor oath required. For personal study only.

โœฆ Synopsis


Hyperbranched polymers are highly branched macromolecules that are prepared through a one-step polymerization process. Many kinds of hyperbranched polymers have been investigated as novel dendritic macromolecules. The general concepts, syntheses and the properties of hyperbranched polymers are reviewed in this article. The polymerization reactions are classiยฎed into three categories: (1) step-growth polycondensation of AB x monomers; and (2) self-condensing vinyl polymerization of AB p monomers; (3) multibranching ring-opening polymerization of latent AB x monomers. Hyperbranched polymers are generally composed of dendritic, linear and terminal units and a degree of branching (DB) helps to describe their structures. It has been shown that most of the hyperbranched polymers possess some of the unique properties exhibit dendritic macromolecules, such as low viscosity, good solubility, and multi-functionality. Owing to multi-functionality, physical properties such as solubility in solvents and the glass transition temperature can be controlled by the chemical modiยฎcation of the end functional groups (endcapping reactions). Applications of designed hyperbranched polymers to speciยฎc ยฎelds are also described.


๐Ÿ“œ SIMILAR VOLUMES


A new class of block polymers
โœ A. V. Tobolsky; A. Rembaum ๐Ÿ“‚ Article ๐Ÿ“… 1964 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 737 KB
Photodeformable Polymers: A New Kind of
โœ Yanlei Yu; Tomiki Ikeda ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 169 KB

## Abstract **Summary:** Starting in the 1960s, several kinds of photodeformable polymers have been developed, such as monolayers, polymer gels, solid films and liquidโ€crystalline elastomers with different photodeformation mechanisms. This field evolved slowly until recently when significant achiev