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Hylleraas-type calculations for lithium

✍ Scribed by Grzegorz Pestka; Wiesław Woźnicki

Book ID
103035612
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
341 KB
Volume
255
Category
Article
ISSN
0009-2614

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✦ Synopsis

The method of superposition of correlated configurations has been used to evaluate the nonrelativistic energies of the 2 2S, 32S, 42S, 22p, 32p, 42p, 32D and 42D states of lithium. The results for 32p, 42p and 42D are the best in the literature. The size of the basis set never exceeds 400 due to a careful optimization of the non-linear parameters. Dipole absorption oscillator strengths and mean lifetimes are also reported.

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