Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis

✍ Scribed by Prof. Dr. Jeffrey Schwartz; Dr. Jay A. Labinger

• Publisher: John Wiley and Sons
• Year: 1976
• Tongue: English
• Weight: 762 KB
• Volume: 15
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.197603331

✦ Synopsis

Abstract

Hydrozirconation has recently been developed as a procedure for functionalizing alkenes, alkynes, and 1,3‐dienes via organozirconium(IV) intermediates. These intermediates react with a variety of electrophilic reagents to give organic products in high yield. Mechanisms of reactions involved in these sequences are discussed.