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Hydroxylamine Oxygen as Nucleophile in Palladium(0)- and Palladium(II)-Catalyzed Allylic Alkylation: A Novel Access to Isoxazolidines.

โœ Scribed by Pedro Merino; Tomas Tejero; Vanni Mannucci; Guillaume Prestat; David Madec; Giovanni Poli


Book ID
102007858
Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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Regio- and stereoselective palladium(0)-
โœ Maryse Rychlet Elliott; Anne-Lise Dhimane; Max Malacria ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 230 KB

Recently, we reported an efficient palladium(0) catalyzed allylation of a non-stabilized nucleophile, lithium enolate of ethyl isobutyrate 2a, with monoepoxide of isoprene la, as a first step in the total synthesis of epiilludol (scheme 1).] The synthetic value of the regio-and stereoselective allyl