Regio- and stereoselective palladium(0)-
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Maryse Rychlet Elliott; Anne-Lise Dhimane; Max Malacria
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Article
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1998
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Elsevier Science
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French
โ 230 KB
Recently, we reported an efficient palladium(0) catalyzed allylation of a non-stabilized nucleophile, lithium enolate of ethyl isobutyrate 2a, with monoepoxide of isoprene la, as a first step in the total synthesis of epiilludol (scheme 1).] The synthetic value of the regio-and stereoselective allyl