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Hydroxyl radicals in aqueous glasses: Characterization and reactivity studied by ESR spectroscopy

✍ Scribed by H Riederer; J Hüttermann; P Boon; M.C.R Symons


Publisher
Elsevier Science
Year
1983
Weight
740 KB
Volume
54
Category
Article
ISSN
0022-2364

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All arrangements and procedures for steady-state and time-resolved ESR were as described in [4]. The radicals Me,C and Me3C02CCH, were generated by photolysis of the corresponding disubstituted ketones. These undergo type-I cleavage from a short-lived triplet state followed by a fast decarbonylation