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Hydroxyacids as efficient chiral spacers for asymmetric intramolecular [2+2] photocycloadditions

✍ Scribed by Sophie Faure; Sylvie Piva-Le Blanc; Olivier Piva; Jean-Pierre Pete

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
200 KB
Volume
38
Category
Article
ISSN
0040-4039

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1,3-Butadiene-2-carboxylates derived from certain chiral alcohols are good substrates for a highly efficient asymmetric Diels-Alder reaction, which permits the preparation of optically active heterocyclic, cyclohexane and hydrindane systems.