The various sources of error involved in the determination of acidity constants using a glass electrode are discussed. The results are extended to the elucidation of metal complex equilibria. It is shown how the best set of equilibria constants may be obtained using a weighted least square method. T
Hydroxamatkomplexe II. Die Anwendung der pH-Methode
✍ Scribed by G. Anderegg; F. L'Eplattenier; G. Schwarzenbach
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 430 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The equilibria between acethydroxamic acid and 16 metal cations, and their complexes have been elucidated. For the results see table 1. The complex Formation of desferri‐ferrioxamine B and desferri‐ferrioxamin E, which are trihydroxamic acids, with various bivalent and trivalent metal ions have been studied in a similar manner. For the results see tables 2 and 3.
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