Hydrothermal Synthesis, Structure, and Magnetic Properties of a Novel Monodimensional Iron Phosphate: [FeF(HPO 4 ) 2 ,N 2 C 3 H 12 ,(H 2 O) x ] ( x ≈ 0.20) (ULM-14)
✍ Scribed by Cavellec, Myriam; Riou, Didier; Grenèche, Jean-Marc; Férey, Gérard
- Book ID
- 121447848
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 157 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A novel layered zinc+cobalt phosphate Zn (2؊x) Co x (HPO 4 ) 3 ' C 3 N 2 H 12 (x:0.05), has been solvothermally synthesized, and its structure determined at 293 K with a Siemens Smart 1000 CCD di4ractometer [monoclinic, P2 1 /c, a ؍ 8.632(2) A > , b ؍ 9.648(4) A > , c ؍ 17.077(6) A > , ؍ 93.
The hydrothermal syntheses and structures of two new open-framework iron phosphates, I, [C 6 N 2 H 14 ][Fe III 2 F 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 ].2H 2 O, II, and [C 6 N 2 H 14 ] 2 [Fe III 3 (OH)F 3 (PO 4 ) (HPO 4 ) 2 ] 2 . H 2 O, are presented. The structures of both I and II consist of FeO 4 F 2 octa