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Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

✍ Scribed by M.John Plater; Mark R. St J. Foreman; R.Alan Howie; Janet M.S. Skakle; Alexandra M.Z. Slawin

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 194 KB
Volume: 315
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(01)00318-8

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✦ Synopsis

Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition 4). Each has a sheet structure with a distorted octahedral coordination environment.

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