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Hydrothermal synthesis, crystal structure and magnetic properties of a DyIII-FeIII heteronuclear complex

✍ Scribed by CHEN, Yanmin; XIE, Qingfan


Book ID
119579983
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
792 KB
Volume
30
Category
Article
ISSN
1002-0721

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FeVO 4 -II, a metastable phase so far produced under high (5), on the other hand, constructed the pressure-product pressures, has been synthesized by a hydrothermal method from diagram of the Fe 1Οͺx V x O 2 system for 0 Υ… x Υ… 0.5 at 800ЊC a solution of VOCl 2 and FeCl 3 . FeVO 4 -II crystallizes in

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## Abstract A new series of oxovanadium(IV)–lanthanide(III) heteronuclear complexes [Yb(H~2~O)~8~]~2~[(VO)~2~(TTHA)]~3~β‹…21 H~2~O (1), {[Ho(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}β‹… 8.5 H~2~O (2), {[Gd(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}β‹…8.5 H~2~O (3), {[Eu(H~2~O)~7~][(VO)~2~(TTHA)]~1.5