Hydrothermal synthesis, crystal structure, and luminescence of lanthanide(III) coordination polymers with tetrafluorosuccinate and 1,10-phenanthroline
β Scribed by Xia Li; Yan-Bin Zhang; Ying-Quan Zou
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 789 KB
- Volume
- 919
- Category
- Article
- ISSN
- 0022-2860
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This paper presents three new lanthanide coordination polymers [Pr 2 (pim) Er, 3) prepared by the hydrothermal reaction. The structural details of complexes 1, 2 and 3 are reported. In complex 1, the Pr(III) ions are bridged by pim in three modes to form 2D layers. Adjacent layers are assembled by
Three novel lanthanide complexes, [Ln 2 (fum) 3 (phen) 2 (H 2 O) 2 ] n (Ln ΒΌ La, 1; Pr, 2. fum ΒΌ fumarate dianion; phen ΒΌ 1,10-phenanthroline) and [Er 2 (fum) 3 (phen) 2 ] n (3), were synthesized hydrothermally and characterized by X-ray crystallography. Single crystal X-ray diffraction analysis sho