Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V15O42(H2O)]·2H2O
✍ Scribed by Xiao-Bing Cui; Ji-Qing Xu; Lan Ding; Hong Ding; Ling Ye; Guo-Yu Yang
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 196 KB
- Volume
- 660
- Category
- Article
- ISSN
- 0022-2860
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Two new coordination compounds [Zn(AZT) 4 (H 2 O) 2 ](PA) 2 •4H 2 O and [Zn(AZT) 2 (H 2 O) 4 ](HTNR) 2 •4H 2 O have been prepared by using AZT (3-azido-1,2,4-triazole) as ligands, PA -(picrate) or HTNR -(anion formed by the deprotonation of one of the two hydroxyl-groups of 2,4,6-trinitroresorcinol)
The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733