A sodium indium hydrogen phosphate hydrate, Na 2 In 2 [PO 3 (OH)] 4 ' H 2 O, was synthesized under mild hydrothermal conditions, and the crystal structure was characterized by the singlecrystal X-ray di4raction method. The structure is of a new type with the following data:
Hydrothermal Synthesis, Crystal Structure, and Characterization of Tetrasodium Tricobalt(II)-bis-Phosphate-bis-Hydrogenophosphate Octahydrate, Na4Co3H2(PO4)4·8H2O, with a New Structure Type
✍ Scribed by Shao-Yu Mao; Ya-Xi Huang; Zan-Bin Wei; Jin-Xiao Mi; Zhong-Le Huang; Jing-Tai Zhao
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 320 KB
- Volume
- 149
- Category
- Article
- ISSN
- 0022-4596
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✦ Synopsis
A sodium cobalt hydrogen phosphate hydrate, Na 4 Co 3 H 2 (PO 4 ) 4 ' 8H 2 O, was synthesized by the mild hydrothermal method, and the crystal structure was characterized by the single-crystal X-ray di4raction method. The layered structure possesses a new type with the following data:
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Using 1, 4, 8, 11-tetraazacyclotetradecane (cyclam) as a template, a new layered zinc phosphate Zn 4 (PO 4 ) 2 (HPO 4 ) 2 ' 0.5(C 10 H 28 N 4 ) ' 2H 2 O (de5ned as ZnPO-cyclam) with 12-ring cavities was synthesized under hydrothermal conditions in a molar ratio ZnO:P 2 O 5 :cyclam:H 2 O ؍ 1:2.2:0.