✦ LIBER ✦

Hydrothermal synthesis and structural studies of two new copper(II) coordination polymers with V-shape ligands

✍ Scribed by Chang-Yan Sun; Lin-Pei Jin

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 449 KB
Volume: 782
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2005.08.015

No coin nor oath required. For personal study only.

✦ Synopsis

Two new coordination polymers, [Cu 2 (oba) 2 (bpy) 2.5 ] n $2nH 2 O (1) and [Cu(bpndc)(bpy) 0.5 ] n (2) (H 2 obaZ4,4 0 -oxybis(benzoic acid); H 2 bpndcZbenzophenone-4,4 0 -dicarboxylic acid; bpyZ4,4 0 -bipyridine) were synthesized by the hydrothermal reactions and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. In 1, oba 2K anions adopt tridentate and bidentate mode, linking Cu(II) ions into 1D helical chains, and bpy ligands link Cu(II) ions into 1D chains too. These two kinds of chains are interconnected in the Cu(II) nodes, forming a complicated 3D network. In 2, bpndc 2K anions adopt tetradentate mode, linking Cu(II) ions into 2D layers. These layers are connected by bpy ligands into a 3D network with small 1D channels.

📜 SIMILAR VOLUMES

Hydrothermal synthesis and structural ch

Hydrothermal synthesis and structural characterization of three helical coordination polymers constructed from V-shaped ligand

✍ Chao Qin; Xinlong Wang; Enbo Wang; Yanfei Qi; Hua Jin; Song Chang; Lin Xu 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 356 KB

Synthesis, Structural Characterization a

Synthesis, Structural Characterization and Properties of Copper(II) and Zinc(II) Coordination Polymers with a New Bridging Chelating Ligand

✍ Guo-Ping Yong; Zhi-Yong Wang; Yong Cui 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

Hydrothermal synthesis and crystal struc

Hydrothermal synthesis and crystal structures of two zinc(II) coordination polymers with benzophenone-4,4′-dicarboxylic acid

✍ Changyan Sun; Linpei Jin 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 295 KB

Two new coordination polymers, [Zn(bpndc)(4,4 0 -bpy) 1.5 ] n $0.5n(4,4 0 -bpy)$0.5nH 2 O (1) and [Zn(bpndc)(phen)(H 2 O)] n (2) (H 2 bpndcZ benzophenone-4,4 0 -dicarboxylic acid; 4,4 0 -bpyZ4,4 0 -bipyridine; phenZ1,10-phenanthroline) were synthesized by the hydrothermal reactions and characterized

Syntheses, Structures, and Magnetic Prop

Syntheses, Structures, and Magnetic Properties of Two Gadolinium(III)–Copper(II) Coordination Polymers by a Hydrothermal Reaction

✍ Yucang Liang; Rong Cao; Weiping Su; Maochun Hong; Wenjian Zhang 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 140 KB 👁 2 views

Syntheses, Structures, and Magnetic Prop

Syntheses, Structures, and Magnetic Properties of Two Gadolinium(III)–Copper(II) Coordination Polymers by a Hydrothermal Reaction

✍ Yucang Liang; Rong Cao; Weiping Su; Maochun Hong; Wenjian Zhang 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 2 views

Hydrothermal synthesis and structural ch

Hydrothermal synthesis and structural characterization of three new transition-metal coordination polymers with 2-carboxycinnamic acid

✍ Chang-Yan Sun; Jie Zhou; Lin-Pei Jin 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 819 KB

Three new coordination polymers, [Zn 2 (CCA) 2 (bpy)] n AE0.5nbpy (1), [Zn(CCA)(bpe)(H 2 O)] n AE0.5nH 2 O (2) and [Mn(CCA)(bpe)] n AE2nH 2 O (3) (H 2 CCA = 2-carboxycinnamic acid; bpy = 4,4 0 -bipyridine; bpe = 1,2-bis(4-pyridyl)ethane) have been synthesized by the hydrothermal reactions and charac